CHITOSAN ISOLATION AND ITS APPLICATION TO REDUCE THE CONTENT OF METAL IONS IN WELLBORE WATER

Yulida Amri, Rahmatul Fajri, Matius Stefanus Batu

Abstract


Potential water sources such as white shrimp shell waste (Penaeus merguiensis) can be used as a source of chitosan. Chitosan can be applied as an environmentally friendly adsorbent for water treatment because of its ability to adsorb metal ions. In this study, chitosan was isolated through several stages such as demineralization, deproteination, decolourization and deacetylation. The yield of chitosan obtained from this study was 17.73%. Characterization by infrared spectroscopy (FTIR) showed the absorption at 3355 cm-1 indicating the presence of amine (-NH2) and hydroxyl (-OH) groups. The absorption of the carbonyl group (-C=O) at 1642 cm-1 disappeared while the absorption of the free amine group (-NH2) at 1590 cm-1 increased indicating the successful deacetylation with a degree of deacetylation (DD) 78%. Application of chitosan in wellbore water did not affect on colour change and decreasing of iron (Fe) content due to low concentration of iron (Fe). However, chitosan can reduce the pH value of water and manganese (Mn) content. The results of ANOVA and DMRT test at 0.05 significance level showed that chitosan with various mass had different effects. The more the mass of chitosan added, the higher the content of manganese (Mn) will decrease.


Keywords


Chitosan; Iron Ion, Manganese Ion; Wellbore Waters

Full Text:

PDF

References


Majekodunmi SO, Olorunsola EO, Ofiwe UC, Udobre AS, Akpan E. Material properties of chitosan from shells of Egeria radiata: Drug delivery considerations. Journal of coastal life medicine. 2017; 5(7): 21-324.

Hou Y, Shavandi A, Carne A, Bekhit A.A, Ng TB, Cheung RCF, Bekhit AEA. Marine shells: Potential opportunities for extraction of functional and health-promoting materials. Critical Reviews in Environmental Science and Technology. 2016; 46 (11-12): 1047-1116

Sinardi, Soewondo P, Notodarmojo S. Pembuatan, karakterisasi dan aplikasi kitosan dari cangkang kerang hijau (Mytulus virdis linneaus) sebagai koagulan penjernih air. Konferensi Nasional Teknik Sipil (KoNTeks 7); 24-26 Oktober 2013; Surakarta; Universitas Sebelas Maret; 2013. P.33-38.

Hamid M. PDAM kota langsa lebih reaktif terhadap masalah air bersih [Internet]. 2017 [cited 2018 Feb 22]. Available from: http://humas.setda.langsakota.go.id/pdam-kota-langsa-lebih-reaktif-terhadap-masalah-air-bersih2017

Said NI. Pembuatan filter untuk menghilangkan zat besi dan mangan dalam air [Internet]. 2018 [cited 2018 Feb 22]. Available from: http://www.kelair.bppt.go.id/Sitpa/Artikel/Filter/filter.html

Kumari S, Rath P, Kumar ASH, Tiwari TN. Extraction and characterization of chitin and chitosan from from fishery waste by chemical method. Environmental Technology & Innovation. 2015; 3(2015): 77-85

Arbia W, Arbia L, Adour L, Amrane A. Chitin recovery using biological methods. Food Technol. Biotechnol. 2013; 51 (1): 12–25

Sjaifullah A, Santoso AB. Autolytic isolation of chitin from white shrimp (Penaues vannamei) waste. Procedia Chemistry. 2016; 18 (2016): 49 – 52

Al-Manhel AJ, Al-Hilphy ARS, Niamah AK. Extraction of chitosan, characterization and its use for water purification. Journal of the Saudi Society of Agricultural Sciences. (2016):1-4

El Knidri H, El Khalfaouy R, Laajeb A, Addaou A, Lahsini A. Eco-friendly extraction and characterization of chitin and chitosan from the shrimp shellwaste via microwave irradiation. Process Safety and Environment Protection. 2016; 104 (Part A): 395-405

Samar MM, El-Kalyoubi MH, Khalaf MM, El-Razik MMA. Physicochemical, functional, antioxidant and antibacterial properties of chitosan extracted from shrimp wastes by microwave technique. Annals of Agricultural Science. 2013: 58(1): 33–41

Majekodunmi SO, Olorunsola EO, Uzoaganobi CC. Comparative physicochemical characterization of chitosan from shells of two bivalved mollusks from two different continents. American Journal of Polymer Science. 2017; 7(1): 15-22

He X, Li K, Xing R, Liu S, Hu L, Li P. The production of fully deacetylated chitosan by compression method. Egyptian Journal of Aquatic Research. 2016; 7(1): 15-22

Kurniasih M, Kartika D. Sintesis dan karakterisasi fisika-kimia kitosan. Jurnal Inovasi. 2011; 5(1): 42-48

Kumari S, Rath PK. Extraction and characterization of chitin and chitosan from (Labeo rohit) fish scales. Procedia Materials Science. 2014; 6(2014): 482- 489

Hendrawati, Sumarni S, Nurhasni. Penggunaan kitosan sebagai koagulan alami dalam perbaikan kualitas air danau. Jurnal KIMIA VALENSI: Jurnal Penelitian dan Pengembangan Ilmu Kimia. Mei 2015; 1(1): 1-11

Suptijah P, Zahiruddin W, Firdaus D. Pemurnian air sumur dengan kitosan melalui tahapan koagulasi dan filtrasi. Buletin Teknologi dan Hasil Perikanan. 2008; 11(1): 65-75

Prambaningrum W, Djunaidi MC. Adsorpsi ion besi (III) dan cadmium (II) menggunakan gel kitosan. Jurnal Kimia Sains dan Aplikasi. 2009; 12 (2) : 47-51




DOI: https://doi.org/10.18860/neu.v12i1.8186

Refbacks

  • There are currently no refbacks.


Copyright (c) 2020 Yulida Amri, Rahmatul Fajri, Matius Stefanus Batu

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

 

Editorial Office of Jurnal Neutrino:
Department of Physics, Faculty of Sains and Technology, Universitas Islam Negeri Maulana Malik Ibrahim Malang, Indonesia
B.J. Habibie 2nd Floor
Gajayana st. No.50 Malang 65144
Telp. +62 813-4090-1818
Email: neutrino@uin-malang.ac.id

 

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License 

View My Stats